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An imidazolium-based fluorescent clophane for the selective recognition of iodide

Suresh, Vangaru, Ahmed, Nisar, Youn, Il Seung and Kim, Kwang S. 2012. An imidazolium-based fluorescent clophane for the selective recognition of iodide. Chemistry - An Asian Journal 7 (4) , pp. 658-663. 10.1002/asia.201100941

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Abstract

For your I's only: A new imidazolium-based fluorescent cyclophane 1 was designed and synthesized that was quenched selectively in the presence of iodide but not other anions, as assessed by fluorimetry. In addition, fluorescence titration experiments, 1H NMR spectroscopic data, and theoretical calculations provide evidence that 1 encapsulates two iodides inside its cavity.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: anion receptors; cyclophanes; fluorescent probes; hydrogen bonds; recognition of iodide
Publisher: Wiley-Blackwell
ISSN: 1861-4728
Last Modified: 07 Jun 2017 10:14
URI: http://orca.cardiff.ac.uk/id/eprint/100432

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