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Synthesis of thioesters by reactions of carboxylic acids with tris(ethylthio)borane

Pelter, Andrew, Levitt, Terence E., Smith, Keith and Jones, Ann 1977. Synthesis of thioesters by reactions of carboxylic acids with tris(ethylthio)borane. Journal of the Chemical Society, Perkin Transactions 1 (14) , pp. 1672-1674. 10.1039/P19770001672

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Abstract

Thioesters are obtained in high yield by reactions of carboxylic acids with tris(ethylthio)borane in a refluxing solvent. The reaction pathway is complex, involving initial production of carboxylic anhydrides and oxybis(diacyloxy-boranes), which are separately attacked by liberated ethanethiol or the excess of tris(ethylthio)borane.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 0300-922X
Last Modified: 04 Jun 2017 02:50
URI: http://orca.cardiff.ac.uk/id/eprint/12614

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