Nickel-catalyzed decyanation of inert carbon–cyano bonds

Patra, Tuhin, Agasti, Soumitra, Akanksha and Maiti, Debabrata 2013. Nickel-catalyzed decyanation of inert carbon–cyano bonds. Chemical Communications 49 (1) , pp. 69-71. 10.1039/c2cc36883h

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Abstract

Nickel catalyzed decyanation of aryl and aliphatic cyanides with hydrosilane as the hydride source has been developed. This method is easy to handle, scalable and can be carried out without a glove box. The method has been applied in the cyanide directed functionalization reaction and α-substitution of benzyl cyanide.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date of Acceptance:	6 November 2012
Last Modified:	06 May 2023 01:58
URI:	https://orca.cardiff.ac.uk/id/eprint/138419

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