Iron-Mediated Decarboxylative Trifluoromethylation of ?,?-Unsaturated Carboxylic Acids with Trifluoromethanesulfinate

Patra, Tuhin, Deb, Arghya, Manna, Srimanta, Sharma, Upendra and Maiti, Debabrata 2013. Iron-Mediated Decarboxylative Trifluoromethylation of ?,?-Unsaturated Carboxylic Acids with Trifluoromethanesulfinate. European Journal of Organic Chemistry 2013 (24) , pp. 5247-5250. 10.1002/ejoc.201300473

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Abstract

A sustainable FeCl3‐mediated method has been developed for the decarboxylative trifluoromethylation of α,β‐unsaturated carboxylic acids by using NaSO2CF3 as an economic and stable CF3 source. The reaction proceeds under mild condition and tolerates various functional groups. Advantageously, this method does not require an inert atmosphere and proceeds well in air at ambient temperature.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Wiley
ISSN:	1434-193X
Last Modified:	06 May 2023 01:58
URI:	https://orca.cardiff.ac.uk/id/eprint/138420

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