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DMSO as a switchable alkylating agent in heteroarene C-H functionalization

Garza-Sanchez, R. Aleyda, Patra, Tuhin, Tlahuext-Aca, Adrian, Strieth-Kalthoff, Felix and Glorius, Frank 2018. DMSO as a switchable alkylating agent in heteroarene C-H functionalization. Chemistry - A European Journal 24 (40) , pp. 10064-10068. 10.1002/chem.201802352

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Abstract

Herein, we report a novel strategy for the activation of DMSO to act as a versatile alkylating agent in heteroarene C−H functionalization. This direct, simple, and mild switch between methylation/trideuteromethylation and methylthiomethylation of heteroarenes was achieved under reagent‐controlled photoredox catalysis conditions. The proposed mechanism is supported by both experimental and computational studies.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Wiley
ISSN: 0947-6539
Last Modified: 17 Feb 2021 15:00
URI: http://orca.cardiff.ac.uk/id/eprint/138435

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