1,5,9,13-Tetraselena[13]ferrocenophane: synthesis, complexation, crystallographic and electrochemical study

Jing, Su, Morley, Christopher Peter, Gu, Cheng-Yun and Di Vaira, Massimo 2010. 1,5,9,13-Tetraselena[13]ferrocenophane: synthesis, complexation, crystallographic and electrochemical study. Dalton Transactions 39 (37) , pp. 8812-8819. 10.1039/c0dt00367k

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Abstract

A novel macrocyclic ferrocenophane, 1,5,9,13-tetraselena[13]ferrocenophane (L), was synthesized. Reaction of L with [M(NCMe)4](PF6)2 (M = Pd and Pt) or [Cu(NCMe)4](PF6) led to complexes [ML](PF6)2 (M = Pd and Pt) or [CuL](PF6). The Ag(I) cation induced the formation of a one-dimensional polymer {[AgL](PF6)}n due to its large ionic radius. The structures of L and its four complexes have been determined by X-ray crystallography. Electrochemical studies showed that, in [ML](PF6)2 (M = Pd and Pt), the half-wave potential of the 1,1′-ferrocenediyl group shifts to much more positive potentials due to the strong through-space interaction between the two metals (MFe).

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1477-9226
Last Modified:	05 Nov 2019 03:27
URI:	https://orca.cardiff.ac.uk/id/eprint/20106

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