Syntheses and Anion Binding Capabilities of Bis(diarylboryl) Ferrocenes and Related Systems

Kelly, Michael J., Broomsgrove, Alexander E.J., Morgan, Ian Rhys ORCID: https://orcid.org/0000-0002-0253-1855, Siewert, Inke, Fitzpatrick, Philip, Smart, Jessica, Vidovic, Dragoslav and Aldridge, Simon 2013. Syntheses and Anion Binding Capabilities of Bis(diarylboryl) Ferrocenes and Related Systems. Organometallics 32 (9) , pp. 2674-2684. 10.1021/om400152x

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Abstract

Isomeric diborylated ferrocenes featuring 1,1′-, 1,2-, and 1,3-substitution patterns have been targeted via a combination of electrophilic aromatic substitution and directed ortho-lithiation protocols. While none of these systems are competent for the Lewis acid chelation of fluoride, related systems featuring a mixed B/Si acceptor set capture 1 equiv of fluoride via a Si–F–B bridging motif.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	American Chemical Society
ISSN:	0276-7333
Last Modified:	24 Oct 2022 11:29
URI:	https://orca.cardiff.ac.uk/id/eprint/48281

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