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A porphyrin-based microporous network polymer that acts as an efficient catalyst for cyclooctene and cyclohexane oxidation under mild conditions

Antonangelo, Ariana R., Bezzu, Grazia, Mughal, Sabeeha S., Malewschik, Talita, McKeown, Neil B. and Nakagaki, Shirley 2017. A porphyrin-based microporous network polymer that acts as an efficient catalyst for cyclooctene and cyclohexane oxidation under mild conditions. Catalysis Communications 99 , p. 100. 10.1016/j.catcom.2017.05.024

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Abstract

The highly efficient dibenzodioxin-forming reaction between the (pentafluorophenyl)porphyrin manganese(III) (MnP) and hexahydroxytriptycene (HHT) provide a new microporous network polymer (P1), which demonstrated a large surface area (1080 m2 g− 1) and proved to be an efficient solid for heterogeneous catalysis for cyclooctene and cyclohexane oxidation under mild conditions and with high capacity of recovery and reuse in many catalytic cycles.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Elsevier
ISSN: 1566-7367
Date of First Compliant Deposit: 18 July 2017
Date of Acceptance: 22 May 2017
Last Modified: 12 Mar 2020 05:08
URI: https://orca.cardiff.ac.uk/id/eprint/102524

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