Patra, Tuhin, Watile, Rahul, Agasti, Soumitra, Naveen, Togati and Maiti, Debabrata
2016.
Sequential meta-C–H olefination of synthetically versatile benzyl silanes: effective synthesis of meta-olefinated toluene, benzaldehyde and benzyl alcohols.
Chemical Communications
52
(10)
, pp. 2027-2030.
10.1039/C5CC09446A
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Official URL: http://dx.doi.org/10.1039/C5CC09446A
Abstract
Tremendous progress has been made towards ortho-selective C–H functionalization in the last three decades. However, the activation of distal C–H bonds and their functionalization has remained fairly underdeveloped. Herein, we report sequential meta-C–H functionalization by performing selective mono-olefination and bis-olefination with late stage modification of the C–Si as well as Si–O bonds. Temporary silyl connection was found to be advantageous due to its easy installation, easy removal and wide synthetic diversification.
Item Type: | Article |
---|---|
Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Publisher: | Royal Society of Chemistry |
ISSN: | 1359-7345 |
Date of First Compliant Deposit: | 18 February 2021 |
Date of Acceptance: | 2 December 2015 |
Last Modified: | 06 May 2023 15:15 |
URI: | https://orca.cardiff.ac.uk/id/eprint/138427 |
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