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Progress in organocatalysis with hypervalent iodine catalysts

Singh, Fateh V., Shetgaonkar, Samata E., Krishnan, Manjula and Wirth, Thomas ORCID: 2022. Progress in organocatalysis with hypervalent iodine catalysts. Chemical Society Reviews 51 (18) , pp. 8102-8139. 10.1039/D2CS00206J

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Hypervalent iodine compounds as environmentally friendly and relatively inexpensive reagents have properties similar to transition metals. They are employed as alternatives to transition metal catalysts in organic synthesis as mild, nontoxic, selective and recyclable catalytic reagents. Formation of C–N, C–O, C–S, C–F and C–C bonds can be seamlessly accomplished by hypervalent iodine catalysed oxidative functionalisations. The aim of this review is to highlight recent developments in the utilisation of iodine(III) and iodine(V) catalysts in the synthesis of a wide range of organic compounds including chiral catalysts for stereoselective synthesis. Polymer-, magnetic nanoparticle- and metal organic framework-supported hypervalent iodine catalysts are also described.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Royal Society of Chemistry
ISSN: 0306-0012
Date of First Compliant Deposit: 27 September 2022
Date of Acceptance: 26 August 2022
Last Modified: 16 Nov 2022 15:43

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