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Precise tuning of cationic cyclophanes toward highly selective fluorogenic recognition of specific biophosphate anions

Yousuf, Muhammad, Ahmed, Nisar, Shirinfar, Bahareh, Miriyala, Vijay Madhav, Youn, Il Seung and Kim, Kwang S. 2014. Precise tuning of cationic cyclophanes toward highly selective fluorogenic recognition of specific biophosphate anions. Organic Letters 16 (8) , pp. 2150-2153. 10.1021/ol500613y

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Abstract

Cationic cyclophanes with bridging and spacer groups possess well-organized semirigid cavities and are able to encapsulate and stabilize anionic species through diverse molecular interactions. We highlight the precise tuning of functionalized cyclophanes toward selective recognition of AMP, GTP, and pyrophosphate (PPi) using fluorescence, NMR spectroscopy, and density functional theory (DFT).

Item Type: Article
Date Type: Published Online
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: ACS
ISSN: 1523-7060
Last Modified: 04 Jun 2017 09:49
URI: http://orca.cardiff.ac.uk/id/eprint/100421

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