Nguyen, Hong K. D., Sankar, Gopinathan and Catlow, Charles Richard A. ORCID: https://orcid.org/0000-0002-1341-1541 2016. Effects of the synthetic condition on the stability, particle size and redox chemistry of nanoporous CoAlPO-34. Journal of Porous Materials 24 (3) , pp. 567-572. 10.1007/s10934-016-0292-y |
Preview |
PDF
- Accepted Post-Print Version
Download (579kB) | Preview |
Official URL: http://dx.doi.org/10.1007/s10934-016-0292-y
Abstract
This study focuses on the effect of the synthetic conditions on the stability, particle size, redox chemistry of cobalt into the framework of CoAlPO-34. It seems that the most sufficient pH for the substitution of Co into the framework of CoAlPO-34 was pH around 7.5 when the as-synthesized bifunctional catalyst has the best redox property. The pH of the initial gel has strong effect on the particle size of CoAlPO-34. The substitution of cobalt and redox chemistry were determined by: EXAFS combined with XRD, XANES, IR. Stability of the nanoporous catalyst studied by in situ XRD were also reported.
Item Type: | Article |
---|---|
Date Type: | Published Online |
Status: | Published |
Schools: | Cardiff Catalysis Institute (CCI) Chemistry |
Subjects: | Q Science > QD Chemistry |
Publisher: | Springer |
ISSN: | 1380-2224 |
Date of First Compliant Deposit: | 19 July 2017 |
Date of Acceptance: | 26 September 2016 |
Last Modified: | 07 Nov 2023 00:18 |
URI: | https://orca.cardiff.ac.uk/id/eprint/102592 |
Actions (repository staff only)
Edit Item |