Possible role for Cu(II) compounds in the oxidation of malonyl dichloride and HCl at Cu(110) surfaces

Davies, Philip Rosser ORCID: https://orcid.org/0000-0003-4394-766X, Edwards, Dyfan and Richards, Darran 2009. Possible role for Cu(II) compounds in the oxidation of malonyl dichloride and HCl at Cu(110) surfaces. Journal of Physical Chemistry. C 113 (24) , pp. 10333-10336. 10.1021/jp903042f

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Abstract

The pathway for the chlorination of Cu(110) surfaces by malonyl dichloride and HCl is changed in the presence of oxygen with STM results suggesting the formation of a surface CuCl2 state at room temperature that may have implications for mechanistic models of the Deacon process and of dioxin formation at aerosol particle surfaces.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Subjects:	Q Science > QD Chemistry
Publisher:	American Chemical Society
ISSN:	1932-7447
Last Modified:	18 Oct 2022 12:34
URI:	https://orca.cardiff.ac.uk/id/eprint/10334

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