On-off porosity switching in a molecular organic solid

Jones, James T. A., Holden, Daniel, Mitra, Tamoghna, Hasell, Tom, Adams, Dave J., Jelfs, Kim E., Trewin, Abbie, Willock, David James ORCID: https://orcid.org/0000-0002-8893-1090, Day, Graeme M., Bacsa, John, Steiner, Alexander and Cooper, Andrew I. 2011. On-off porosity switching in a molecular organic solid. Angewandte Chemie. International Edition 50 (3) , pp. 749-753. 10.1002/anie.201006030

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Abstract

Pulling the old switcheroo: Microporosity can be switched “on” and “off” in a crystalline molecular organic solid composed of cage molecules (see scheme). The switch is facilitated by conformational flexibility in the soft organic crystal state.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Advanced Research Computing @ Cardiff (ARCCA) Cardiff Catalysis Institute (CCI) Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	conformers; cooperative diffusion; microporous materials; molecular cages
Publisher:	Wiley-Blackwell
ISSN:	1433-7851
Last Modified:	18 Oct 2022 12:45
URI:	https://orca.cardiff.ac.uk/id/eprint/11095

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