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On-off porosity switching in a molecular organic solid

Jones, James T. A., Holden, Daniel, Mitra, Tamoghna, Hasell, Tom, Adams, Dave J., Jelfs, Kim E., Trewin, Abbie, Willock, David James, Day, Graeme M., Bacsa, John, Steiner, Alexander and Cooper, Andrew I. 2011. On-off porosity switching in a molecular organic solid. Angewandte Chemie. International Edition 50 (3) , pp. 749-753. 10.1002/anie.201006030

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Pulling the old switcheroo: Microporosity can be switched “on” and “off” in a crystalline molecular organic solid composed of cage molecules (see scheme). The switch is facilitated by conformational flexibility in the soft organic crystal state.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Advanced Research Computing @ Cardiff (ARCCA)
Cardiff Catalysis Institute (CCI)
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: conformers; cooperative diffusion; microporous materials; molecular cages
Publisher: Wiley-Blackwell
ISSN: 1433-7851
Last Modified: 04 Jun 2017 02:24

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