Alternative strategies with iodine: fast access to previously inaccessible iodine(III) compounds

Hokamp, Tobias, Mollari, Leonardo, Wilkins, Lewis C., Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831 and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2018. Alternative strategies with iodine: fast access to previously inaccessible iodine(III) compounds. Angewandte Chemie International Edition 57 (27) , pp. 8306-8309. 10.1002/anie.201804642

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Abstract

Non‐iodinated arenes are easily and selectively converted into (diacetoxyiodo)arenes in a single step under mild conditions using iodine triacetates as reagents. The oxidative step is decoupled from the synthesis of hypervalent iodine(III) reagents which can now be prepared conveniently in a one‐pot synthesis for subsequent reactions without prior purification. The chemistry of iodine triacetates was also expanded to heteroatom ligand exchanges to form novel inorganic hypervalent iodine compounds.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Wiley
ISSN:	1433-7851
Date of First Compliant Deposit:	15 May 2018
Date of Acceptance:	9 May 2018
Last Modified:	25 Nov 2024 12:00
URI:	https://orca.cardiff.ac.uk/id/eprint/111449

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