Flow synthesis of iodonium trifluoroacetates through direct oxidation of iodoarenes by Oxone®

Soldatova, Natalia S., Postnikov, Pavel S., Yusubov, Mekhman S. and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2019. Flow synthesis of iodonium trifluoroacetates through direct oxidation of iodoarenes by Oxone®. European Journal of Organic Chemistry 2019 (10) , pp. 2081-2088. 10.1002/ejoc.201900220

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Abstract

Flow chemistry is considered to be a versatile and complementary methodology for the preparation of valuable organic compounds. We describe a straightforward approach for the synthesis of iodonium trifluoroacetates through the direct oxidation of iodoarenes in a simple flow reactor using an Oxone‐filled cartridge. Optimization has been carried out using the Nelder–Mead algorithm. The procedure allows a wide range of iodonium salts to be prepared from simple starting materials.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Wiley
ISSN:	1434-193X
Date of First Compliant Deposit:	8 April 2019
Date of Acceptance:	12 February 2019
Last Modified:	26 Nov 2024 19:00
URI:	https://orca.cardiff.ac.uk/id/eprint/121595

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