Structurally defined α-Tetralol-Based chiral hypervalent iodine reagents

Hokamp, Tobias and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2019. Structurally defined α-Tetralol-Based chiral hypervalent iodine reagents. Journal of Organic Chemistry 84 (13) , pp. 8674-8682. 10.1021/acs.joc.9b01315

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Abstract

A novel class of chiral hypervalent iodine reagents containing an α-tetralol-scaffold is being introduced. Iodine triacetate is employed in a key-step as highly selective and efficient iodinating reagent for a short and convenient synthesis of iodine(III) derivatives. Solid state X-ray analyses offer valuable structural information while reactivities and stereoselectivities are investigated in three model reactions.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	American Chemical Society
ISSN:	0022-3263
Funders:	Fonds der Chemischen Industrie
Date of First Compliant Deposit:	19 June 2019
Date of Acceptance:	9 June 2019
Last Modified:	20 Nov 2024 09:00
URI:	https://orca.cardiff.ac.uk/id/eprint/123568

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