Direct formation, and reactions of a carbonyl anion free from competitive nucleophiles

Smith, Keith ORCID: https://orcid.org/0000-0003-4838-5651 and Swaminathan, Kalyanaraman 1976. Direct formation, and reactions of a carbonyl anion free from competitive nucleophiles. Journal of the Chemical Society. Chemical communications (11) , pp. 387-388. 10.1039/C39760000387

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Abstract

At low temperature, in tetrahydrofuran (THF)–ether-pentane, ButLi abstracts a proton from bis(isopropyl)formamide to give LiCONPri2, which reacts with carbonyl compounds to give high yields of α-hydroxyamides.

Item Type:	Article
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	0022-4936
Last Modified:	04 Jun 2017 02:50
URI:	https://orca.cardiff.ac.uk/id/eprint/12606

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