Synthesis and chemiluminescent evaluation of a series of phenyl N-alkylacridinium 9-carboxylates

Batmanghelich, Shariar, Woodhead, J. Stuart, Smith, Keith and Weeks, Ian ORCID: https://orcid.org/0000-0002-6362-2929 1991. Synthesis and chemiluminescent evaluation of a series of phenyl N-alkylacridinium 9-carboxylates. Journal of Photochemistry and Photobiology A: Chemistry 56 (2-3) , pp. 249-254. 10.1016/1010-6030(91)80025-D

Full text not available from this repository.

Abstract

The nitrogen atom of phenyl acridine-9-carboxylate was alkylated with several alkylating agents using thermal, photochemical and sonochemical techniques. Thermal reactions were only suitable for methylation and ethylation, but irradiation with UV light for ultrasound allowed the synthesis of n-propyl iso-propyl and benzyl derivatives. Use of ultrasound produced cleaner product mixtures than UV irradiation. The quantum yields and kinetics of the chemiluminescent reactions of the products with alkaline hydrogen peroxide were found to be independent of the nature of the N-alkyl group.

Item Type:	Article
Status:	Published
Schools:	Chemistry Medicine Systems Immunity Research Institute (SIURI)
Subjects:	Q Science > QD Chemistry
Publisher:	Elsevier
ISSN:	1010-6030
Last Modified:	18 Oct 2022 13:09
URI:	https://orca.cardiff.ac.uk/id/eprint/12654

Citation Data

Cited 15 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item