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Photooxidation of a twisted isoquinolinone

Li, Gang, Zhao, Jianfeng, Yang, Shufan, Li, Yongxin, Rakesh, Ganguly and Zhang, Qichun 2018. Photooxidation of a twisted isoquinolinone. Chemistry - An Asian Journal 13 (3) , pp. 250-254. 10.1002/asia.201701674

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Abstract

Understanding the oxidation mechanism and positions of twistacenes and twistheteroacenes under ambient conditions is very important because such knowledge can guide us to design and synthesize novel, larger stable analogues. Herein, we demonstrated for the first time that a twisted isoquinolinone can decompose under oxygen and light at room temperature. The as‐decomposed product 1 was fully characterized through conventional methods as well as single‐crystal structure analysis. Moreover, the physical properties of the as‐obtained product were carefully investigated and the possible formation mechanism was proposed.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Wiley
ISSN: 1861-4728
Date of First Compliant Deposit: 14 January 2020
Date of Acceptance: 24 December 2017
Last Modified: 16 Mar 2020 06:37
URI: http://orca.cardiff.ac.uk/id/eprint/128488

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