Asymmetric ketone hydroboration catalyzed by alkali metal complexes derived from BINOL ligands

Willcox, Darren, Carden, Jamie L., Ruddy, Adam J., Newman, Paul D. ORCID: https://orcid.org/0000-0002-1808-1211 and Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831 2020. Asymmetric ketone hydroboration catalyzed by alkali metal complexes derived from BINOL ligands. Dalton Transactions 49 (8) , pp. 2417-2420. 10.1039/D0DT00232A

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Abstract

The ability of alkali metal complexes featuring functionalized BINOL-derived ligands to catalyze ketone hydroboration reactions was explored. The reduced products were formed in excellent yield and with variable enantioselectivities dependent upon the nature of the ligand and the alkali metal cation.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1477-9226
Funders:	EPSRC and EP/R026912/1
Date of First Compliant Deposit:	13 February 2020
Date of Acceptance:	22 January 2020
Last Modified:	17 Nov 2023 18:48
URI:	https://orca.cardiff.ac.uk/id/eprint/129618

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