Carter, Emma ![]() ![]() ![]() ![]() |
Abstract
The role of H-bonds in controlling the binding mode of epoxides, namely propylene oxide (3) and cis-2,3-epoxybutane (4), to the vanadyl salen-type complexes, N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino-vanadium (IV) oxide, [VO(1)], and VO(3,5-tBu2-salophen), [VO(2)], have been examined using cw-EPR, cw-ENDOR and HYSCORE spectroscopy. One of the methine protons from the cyclohexyl backbone in [VO(1)] has previously been shown to form a weak H-bond with the epoxide oxygen atom. The absence of this methine proton in the salophen derivative [VO(2)] removes this H-bonding ability of the complex and in turn weakens the epoxide interaction.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Advanced Research Computing @ Cardiff (ARCCA) Chemistry Cardiff Catalysis Institute (CCI) |
Subjects: | Q Science > QD Chemistry |
Publisher: | Elsevier |
ISSN: | 0009-2614 |
Funders: | EPSRC |
Last Modified: | 03 Dec 2022 11:19 |
URI: | https://orca.cardiff.ac.uk/id/eprint/12970 |
Citation Data
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