Metastable linkage isomerism in [Ni(Et4dien)(NO2)2]: a combined thermal and photocrystallographic structural investigation of a Nitro/Nitrito interconversion

Hatcher, Lauren E. ORCID: https://orcid.org/0000-0002-1549-9727, Warren, Mark R., Allan, David R., Brayshaw, Simon K., Johnson, Andrew L., Fuertes, Sara, Schiffers, Stefanie, Stevenson, Anna J., Teat, Simon J., Woodall, Christopher H. and Raithby, Paul R. 2011. Metastable linkage isomerism in [Ni(Et4dien)(NO2)2]: a combined thermal and photocrystallographic structural investigation of a Nitro/Nitrito interconversion. Angewandte Chemie International Edition 50 (36) , pp. 8371-8374. 10.1002/anie.201102022

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Abstract

One way or another: The N‐bound NO2 group in [Ni(Et4dien)(η2‐O,ON)(η1‐NO2)] (see structure Ni turquoise, N blue, O red) has been shown to undergo reversible conversion into the O‐bound nitrito linkage isomer under both thermal and photoactivation of a single crystal. Et4dien=N,N,N′,N′‐tetraethyldiethylenetriamine.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Wiley
ISSN:	1433-7851
Last Modified:	07 Nov 2022 09:52
URI:	https://orca.cardiff.ac.uk/id/eprint/130472

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