A high pressure investigation of the order-disorder phase transition and accompanying spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)

Shepherd, Helena, Tonge, George, Hatcher, Lauren ORCID: https://orcid.org/0000-0002-1549-9727, Bryant, Mathew, Knichal, Jane, Raithby, Paul, Halcrow, Malcolm, Kulmaczewski, Rafal, Gagnon, Kevin and Teat, Simon 2016. A high pressure investigation of the order-disorder phase transition and accompanying spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine). Magnetochemistry 2 (1) , -. 10.3390/magnetochemistry2010009

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Abstract

A high pressure single crystal X-ray diffraction and Raman spectroscopy study has revealed a similar mechanism for both thermal and pressure-induced spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine) and the concomitant anion order-disorder transition.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
ISSN:	2312-7481
Date of First Compliant Deposit:	18 March 2020
Date of Acceptance:	2 February 2016
Last Modified:	05 May 2023 10:00
URI:	https://orca.cardiff.ac.uk/id/eprint/130485

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