A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media: a structural, spectroscopic and theoretical analysis

Harding, Lindsay P., McRobbie, Asuka A. T., Riis-Johannessen, T., Pope, Simon J. A. ORCID: https://orcid.org/0000-0001-9110-9711, Rice, Craig R., Rollinson, Donna and Whitehead, Martina 2020. A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media: a structural, spectroscopic and theoretical analysis. Journal of Chemical Research 44 (11-12) , pp. 733-737. 10.1177/1747519820917888

Preview

PDF - Accepted Post-Print Version Download (1MB) | Preview

Abstract

A Re(I) complex of 3,3′-diamino-2,2′-bipyridine reacts irreversibly with aldehydes and unhindered ketones in water to form bis-aminal cyclised derivatives with the solid-state structure of the reaction with benzaldehyde reported. This reaction produces a Re(I) complex which is significantly more emissive than the starting compound.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Science reviews
ISSN:	1747-5198
Date of First Compliant Deposit:	15 June 2020
Date of Acceptance:	19 May 2020
Last Modified:	16 Nov 2024 10:45
URI:	https://orca.cardiff.ac.uk/id/eprint/132459

Actions (repository staff only)

Edit Item