Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media: a structural, spectroscopic and theoretical analysis

Harding, Lindsay P., McRobbie, Asuka A. T., Riis-Johannessen, T., Pope, Simon J. A., Rice, Craig R., Rollinson, Donna and Whitehead, Martina 2020. A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media: a structural, spectroscopic and theoretical analysis. Journal of Chemical Research 44 (11-12) , pp. 733-737. 10.1177/1747519820917888

[img]
Preview
PDF - Accepted Post-Print Version
Download (1MB) | Preview

Abstract

A Re(I) complex of 3,3′-diamino-2,2′-bipyridine reacts irreversibly with aldehydes and unhindered ketones in water to form bis-aminal cyclised derivatives with the solid-state structure of the reaction with benzaldehyde reported. This reaction produces a Re(I) complex which is significantly more emissive than the starting compound.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Science reviews
ISSN: 1747-5198
Date of First Compliant Deposit: 15 June 2020
Date of Acceptance: 19 May 2020
Last Modified: 25 Nov 2020 21:58
URI: http://orca.cardiff.ac.uk/id/eprint/132459

Actions (repository staff only)

Edit Item Edit Item