Selenocyclizations: control by coordination and by the counterion

Khokhar, Shaista S. and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2004. Selenocyclizations: control by coordination and by the counterion. Angewandte Chemie - International Edition 43 (5) , pp. 631-633. 10.1002/anie.200352884

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Abstract

Selective cyclizations of selenium electrophiles lead to either tetrahydrofurans or lactones (see scheme), depending on the counterions and additives. Modification of the selenium electrophiles allow selective cyclizations, irrespective of the reaction conditions applied.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	Alkenes ; Electrophiles ; Heterocycles ; Selenium ; Stereoselective synthesis
Publisher:	Wiley-Blackwell
ISSN:	1433-7851
Last Modified:	17 Oct 2022 08:53
URI:	https://orca.cardiff.ac.uk/id/eprint/1373

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