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Glycerol/dodecanol double pickering emulsions stabilized by polystyrene-grafted silica canoparticles for interfacial catalysis

Shi, Hui, Fan, Zhaoyu, Ponsinet, Virginie, Sellier, Remi, Liu, Honglai, Pera-Titus, Marc and Clacens, Jean-Marc 2015. Glycerol/dodecanol double pickering emulsions stabilized by polystyrene-grafted silica canoparticles for interfacial catalysis. ChemCatChem 7 (20) , pp. 3229-3233. 10.1002/cctc.201500556

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Abstract

Polystyrene‐grafted silica nanoparticles bearing sulfonic acid centers and with tunable amphiphilic properties were designed to perform the biphasic etherification reaction of glycerol with dodecanol at the interface of Pickering emulsions. By optimizing the hydrophobic properties of the particles, double Pickering emulsions could be generated allowing a facilitated diffusion of glycerol and dodecanol into the microenvironment near the acid centers.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Publisher: Wiley
ISSN: 1867-3880
Last Modified: 11 Jan 2021 16:30
URI: http://orca.cardiff.ac.uk/id/eprint/137434

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