Aquivion®–carbon composites via hydrothermal carbonization: amphiphilic catalysts for solvent-free biphasic acetalization

Fang, Wenhao, Fan, Zhaoyu, Shi, Hui, Wang, Sheng, Shen, Wei, Xu, Hualong, Clacens, Jean-Marc, De Campo, Floryan, Liebens, Armin and Pera-Titus, Marc 2016. Aquivion®–carbon composites via hydrothermal carbonization: amphiphilic catalysts for solvent-free biphasic acetalization. Journal of Materials Chemistry A 4 (12) , pp. 4380-4385. 10.1039/C5TA09705C

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Abstract

One-pot hydrothermal carbonization of polysaccharides (i.e. guar gum or cellulose) with Aquivion® perfluorosulfonic superacid at 180 °C produced new amphiphilic Aquivion®–carbon composites. The materials stabilized dodecyl aldehyde/ethyleneglycol Pickering emulsions, and thus efficiently catalyzed the solvent-free biphasic acetalization reaction under moderate conditions with excellent reusability.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Publisher:	Royal Society of Chemistry
ISSN:	2050-7488
Date of Acceptance:	20 February 2016
Last Modified:	11 Jan 2021 16:30
URI:	https://orca.cardiff.ac.uk/id/eprint/137435

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