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Direct catalytic conversion of furfural to furan-derived amines in the presence of Ru-based Catalyst

Jiang, Shi, Ramdani, Wahiba, Muller, Eric, Ma, Changru, Pera Titus, Marc, Jerôme, François and De Oliveira Vigiera, Karine 2020. Direct catalytic conversion of furfural to furan-derived amines in the presence of Ru-based Catalyst. ChemSusChem 13 (7) , pp. 1699-1704. 10.1002/cssc.202000003

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Abstract

The production of amine intermediates from biomass is capturing increasing attention. Herein, a simple and efficient preparation of l furan‐derived amines was developed [e.g., 1‐(furan‐2‐yl)‐4‐methylpentan‐2‐amine] with high yield (up to 95 %) from (E)‐1‐(furan‐2‐yl)‐5‐methylhex‐1‐en‐3‐one. The catalyst used was Ru/C, and it was recyclable up to the fourth cycle. To further realize cost‐efficiency, a one‐reactor tandem concept was attempted. To this aim direct reaction from furfural was investigated. A high yield (74 %) towards 1‐(furan‐2‐yl)‐4‐methylpentan‐2‐amine could be achieved starting directly from furfural in the presence of methyl isobutyl ketone, NH3, H2, and Ru/C catalyst.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Publisher: Wiley
ISSN: 1864-5631
Last Modified: 11 Jan 2021 12:15
URI: http://orca.cardiff.ac.uk/id/eprint/137479

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