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Overriding ortho selectivity by template assisted meta-C-H activation of benzophenones

Casali, Emanuele, Kalra, Prakriti, Brochetta, Massimo, Borsari, Tania, Gandini, Andrea, Patra, Tuhin, Zanoni, Giuseppe and Maiti, Debabrata 2020. Overriding ortho selectivity by template assisted meta-C-H activation of benzophenones. Chemical Communications 56 (53) , pp. 7281-7284. 10.1039/D0CC03172K

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Abstract

An orthogonal selectivity for distal meta-C–H activation of benzophenone is acheived by overriding the inherent proximal ortho-selectivity through a template assisted metalation approach. This strategy has been successfully utilized in Pd-catalyzed regioselective C–C and C–Si bond formation.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: RSC Publishing
ISSN: 1359-7345
Date of Acceptance: 19 May 2020
Last Modified: 15 Feb 2021 11:12
URI: http://orca.cardiff.ac.uk/id/eprint/138438

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