New reagent systems for electrophilic chlorination of aromatic compounds: organic chlorine-containing compounds in the presence of silica

Smith, Keith ORCID: https://orcid.org/0000-0003-4838-5651, Butters, Michael, Paget, Walter E. and Nay, Barry 1985. New reagent systems for electrophilic chlorination of aromatic compounds: organic chlorine-containing compounds in the presence of silica. Synthesis (Stuttgart) (12) , pp. 1155-1156. 10.1055/s-1985-31461

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Abstract

In the presence of silica, a number of chlorine-containing organic compounds, such as N,N-dichlorourethane, dichloramine-T, and t-butyl hypochlorite, become active electrophilic reagents capable of controlled monochlorination of aromatic compounds under mild conditions; for example, t-butyl hypochlorite/silica chlorinates alkylbenzenes, naphthalene, and anisole readily at 25°C; N,N-dichlorourethane/silica chlorinates benzene within 2 days 50°C.

Item Type:	Article
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Georg Thieme Verlag
ISSN:	0039-7881
Last Modified:	04 Jun 2017 02:57
URI:	https://orca.cardiff.ac.uk/id/eprint/14535

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