Self-Assembly of Heterobimetallic d-f Hybrid Complexes: Sensitization of Lanthanide Luminescence by d-Block Metal-to-Ligand Charge-Transfer Excited States

Pope, Simon J. A. ORCID: https://orcid.org/0000-0001-9110-9711, Coe, Benjamin J., Faulkner, Stephen, Bichenkova, Elena V., Yu, Xuan and Douglas, Kenneth T. 2004. Self-Assembly of Heterobimetallic d-f Hybrid Complexes: Sensitization of Lanthanide Luminescence by d-Block Metal-to-Ligand Charge-Transfer Excited States. Journal of the American Chemical Society 126 (31) , pp. 9490-9491. 10.1021/ja047523h

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Abstract

Carboxylate-bearing d-transition metal bipyridyls form ternary complexes with seven-coordinate lanthanide centers. The neodymium,- ytterbium-, and erbium-containing complexes exhibit lanthanide-centered emissions sensitized by the MLCT states of the d-block components.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	American Chemical Society
ISSN:	0002-7863
Last Modified:	17 Oct 2022 08:55
URI:	https://orca.cardiff.ac.uk/id/eprint/1461

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