Au-Pd separation enhances bimetallic catalysis of alcohol oxidation

Huang, Xiaoyang, Akdim, Ouardia, Douthwaite, Mark, Wang, Kai, Zhao, Liang, Lewis, Richard J., Pattisson, Samuel, Daniel, Isaac T., Miedziak, Peter J., Shaw, Greg, Morgan, David J. ORCID: https://orcid.org/0000-0002-6571-5731, Althahban, Sultan M., Davies, Thomas E., He, Qian ORCID: https://orcid.org/0000-0003-4891-3581, Wang, Fei, Fu, Jile, Bethell, Donald, McIntosh, Steven, Kiely, Christopher J. and Hutchings, Graham J. ORCID: https://orcid.org/0000-0001-8885-1560 2022. Au-Pd separation enhances bimetallic catalysis of alcohol oxidation. Nature 603 , pp. 271-275. 10.1038/s41586-022-04397-7

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Abstract

In oxidation reactions catalysed by supported metal nanoparticles with oxygen as the terminal oxidant, the rate of the oxygen reduction can be a limiting factor. This is exemplified by the oxidative dehydrogenation of alcohols, an important class of reactions with modern commercial applications1–3. Supported gold nanoparticles are highly active for the dehydrogenation of the alcohol to an aldehyde4 but are less effective for oxygen reduction5,6. In contrast, supported palladium nanoparticles are less active than gold for dehydrogenation but offer high efficacy for oxygen reduction5,6. This imbalance can be overcome by alloying gold with palladium which gives enhanced activity to both reactions7,8; however, the electrochemical potential of the alloy is a compromise between that of the two metals meaning that although the oxygen reduction is improved in the alloy, the dehydrogenation activity is poorer. Here we show that by separating the gold and palladium components in bimetallic carbon-supported catalysts we can almost double the reaction rate beyond that achieved with a corresponding alloy catalyst. We demonstrate this using physical mixtures of carbon-supported monometallic gold and palladium and a bimetallic catalyst comprising separated gold and palladium regions. Furthermore, we demonstrate electrochemically that this enhancement is attributable to the coupling of separate redox processes occurring at isolated gold and palladium sites. The discovery of this novel catalytic effect, a cooperative redox enhancement (CORE), offers a new approach to the design of multi-component heterogeneous catalysts.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Publisher:	Nature Research
ISSN:	0028-0836
Funders:	Cardiff University and the Max Planck Centre for Fundamental Heterogeneous Catalysis (FUNCAT)
Date of First Compliant Deposit:	27 January 2022
Date of Acceptance:	4 January 2022
Last Modified:	22 Apr 2024 19:35
URI:	https://orca.cardiff.ac.uk/id/eprint/147017

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