Transesterification of cyclic carbonates to Dimethyl Carbonate using solid oxide catalyst at ambient conditions: environmentally benign synthesis

Meenakshisundaram, Sankar ORCID: https://orcid.org/0000-0002-7105-0203, Satav, Srikanth and Manikandan, Palanichamy 2010. Transesterification of cyclic carbonates to Dimethyl Carbonate using solid oxide catalyst at ambient conditions: environmentally benign synthesis. ChemSusChem 3 (5) 10.1002/cssc.201000038

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Abstract

Continuous synthesis at ambient conditions: Dimethyl carbonate (DMC) is an important methylating and carbonylating agent. Transesterification of cyclic carbonates using methanol for the synthesis of DMC is environmentally benign. CaO–ZnO catalysts, prepared by a wet impregnation method, are effective catalysts for the transesterification of ethylene carbonate using methanol in batch and in continuous reactors. Yields of ca. 84 % DMC can be achieved at ambient conditions.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry Research Institutes & Centres > Cardiff Catalysis Institute (CCI)
Publisher:	Wiley
ISSN:	1864-5631
Last Modified:	19 Jul 2023 11:00
URI:	https://orca.cardiff.ac.uk/id/eprint/154953

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