Dalton communications. Organometallic liquid crystals based on octahedral rhodium(III)

Rourke, J.P. ORCID: https://orcid.org/0000-0002-8961-1021, Bruce, D.W. and Marder, T.B. 1995. Dalton communications. Organometallic liquid crystals based on octahedral rhodium(III). JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (2) , pp. 317-318. 10.1039/dt9950000317

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Abstract

Reaction of mesomorphic alkynes with [RhMe(PMe3)4] led to the RhIII complexes mer,trans-[RhH(alkynyl)2(PMe3)3] which are liquid crystalline; they are rare examples of rod-like liquid crystals based on an octahedral metal centre and represent a unique homologous series of mesomorphic metal complexes containing a hydrido function.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
ISSN:	0300-9246
Last Modified:	05 Apr 2023 14:15
URI:	https://orca.cardiff.ac.uk/id/eprint/155201

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