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Trans-(eta-2-alkene)(4'-alkyloxy-4-stilbazole)dichloroplatinum - low melting organometallic mesogens

Rourke, J.P. ORCID: https://orcid.org/0000-0002-8961-1021, Fanizzi, F.P., Salt, N.J.S., Bruce, D.W., Dunmur, D.A. and Maitlis, P.M. 1990. Trans-(eta-2-alkene)(4'-alkyloxy-4-stilbazole)dichloroplatinum - low melting organometallic mesogens. Journal of the chemical society-chemical communications (3) , pp. 229-231. 10.1039/c39900000229

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Abstract

trans-[PtCl2(CnH2n+1OC6H4CH[double bond, length half m-dash]CHC5H4N)(η2-CH2[double bond, length half m-dash]CHCmH2m+1)](2) form stable smectic A mesophases on heating (for n[gt-or-equal]7, m[gt-or-equal]7; n[gt-or-equal]8, m[gt-or-equal]5; n[gt-or-equal]9, m[gt-or-equal]2; and n[gt-or-equal]11, m[gt-or-equal]0); melting temperatures below 50 °C can easily be achieved.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
ISSN: 00224936
Last Modified: 03 Apr 2023 15:45
URI: https://orca.cardiff.ac.uk/id/eprint/155203

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