λ3-Iodanes as visible light photocatalyst in thioacetalization of aldehydes

Choudhuri, Khokan, Pramanik, Milan and Mal, Prasenjit 2019. λ3-Iodanes as visible light photocatalyst in thioacetalization of aldehydes. European Journal of Organic Chemistry 2019 (30) , pp. 4822-4826. 10.1002/ejoc.201900753

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Abstract

Introduction of an iodine(III) reagent as visible-light photocatalyst for chemoselective dithioacetalization has been the limelight of the current methodology. The mechanistic investigations reveal that the reactions proceeded via radical pathway upon light induced hemolytic cleavage of C–I bond of the catalyst. Several dithioacetals were easily accessible at room temperature and environmentally benign condition.

Item Type:	Article
Date Type:	Published Online
Status:	Published
Schools:	Schools > Chemistry
Publisher:	Wiley
ISSN:	1434-193X
Date of First Compliant Deposit:	10 January 2023
Date of Acceptance:	4 July 2019
Last Modified:	11 Jan 2023 12:47
URI:	https://orca.cardiff.ac.uk/id/eprint/155245

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