Isodesmic metathesis chemistry: A novel way to recycle P(V)

Boruah, Tribani, Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831 and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2023. Isodesmic metathesis chemistry: A novel way to recycle P(V). Chem Catalysis 3 (8) , 100731. 10.1016/j.checat.2023.100731

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Abstract

Since the P=O bond is thermodynamically inert, reducing phosphine oxides to phosphines is notoriously challenging. This preview highlights the recent findings of Xue et al., who describe, through thermodynamic and mechanistic investigation, a novel synthetic pathway for reducing phosphine oxide by employing isodesmic reactions without stoichiometric activators.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Publisher:	Cell Press
ISSN:	2667-1093
Date of First Compliant Deposit:	23 August 2023
Date of Acceptance:	31 July 2023
Last Modified:	22 Aug 2024 21:36
URI:	https://orca.cardiff.ac.uk/id/eprint/162003

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