Reactivity of a series of triaryl borates, B(OAr x) 3, in hydroboration catalysis

Sokolnicki, Tomasz, Alharbi, Mashael M., van Ingen, Yara, Rahim, Shahnaz, Pramanik, Milan, Roldan Martinez, Alberto ORCID: https://orcid.org/0000-0003-0353-9004, Walkowiak, Jędrzej and Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831 2023. Reactivity of a series of triaryl borates, B(OAr x) 3, in hydroboration catalysis. Dalton Transactions 52 (44) , pp. 16118-16122. 10.1039/d3dt03333c

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Abstract

In this paper, we compare the reactivity of a series of triaryl borates B(OArx)3 as catalysts for the hydroboration of alkenes and alkynes. It was observed that commercially available B(OPh)3 performed the poorest, whereas catalysts with o-F atoms appeared to perform much better.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry Research Institutes & Centres > Cardiff Catalysis Institute (CCI)
Additional Information:	License information from Publisher: LICENSE 1: URL: http://creativecommons.org/licenses/by/3.0/, Start Date: 2023-10-20
Publisher:	Royal Society of Chemistry
ISSN:	1477-9226
Date of First Compliant Deposit:	31 October 2023
Date of Acceptance:	15 October 2023
Last Modified:	30 Jun 2024 23:18
URI:	https://orca.cardiff.ac.uk/id/eprint/163575

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