Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue

Aldridge, Simon, Jones, Cameron, Gans-Eichler, Timo, Stasch, Andreas ORCID: https://orcid.org/0000-0002-7407-8287, Kays, Deborah L. ORCID: https://orcid.org/0000-0002-4616-6001, Coombs, Natalie D. and Willock, David J. ORCID: https://orcid.org/0000-0002-8893-1090 2006. Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue. Angewandte Chemie - International Edition 45 (37) , pp. 6118-6122. 10.1002/anie.200602162

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Abstract

Charge changes everything: The cationic terminal aminoborylene complex [CpFe(CO)2(BNCy2)]+[BArF4]− (1, Cy= cyclohexyl, ArF=3,5-(CF3)2C6H3; Fe orange, B green, N blue, O red, C gray) was structurally characterized. DFT studies (see HOMO−2) indicate delocalized π bonding along the linear Fe-B-N framework and significant FeB and BN multiple-bond character.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Wiley
ISSN:	1433-7851
Last Modified:	12 Jul 2024 11:30
URI:	https://orca.cardiff.ac.uk/id/eprint/170278

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