Bis[μ3-1,8-bis-(triisopropyl-silyl-amido)-naphthalene] -bis-(tetra-hydro-furan)di-μ3-oxido-dimanganese(III)disodium

Blake, A.J., Harris, N.A., Kays, D.L. ORCID: https://orcid.org/0000-0002-4616-6001, Lewis, W. and Moxey, G.J. 2010. Bis[μ3-1,8-bis-(triisopropyl-silyl-amido)-naphthalene] -bis-(tetra-hydro-furan)di-μ3-oxido-dimanganese(III)disodium. Acta Crystallographica Section C: Crystal Structure Communications 66 (8) , m204-m206. 10.1107/s010827011002442x

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Abstract

The solid-state structure of the title compound, [Na2Mn2(C32H56N2OSi2)2O2] or [1,8-C10H6(NSiiPr3)2Mn(μ3-O)Na(THF)]2, which lies across a crystallographic twofold axis, exhibits a central [Mn2O2Na2]4+ core, with two oxide groups, each triply bridging between the two MnIII ions and an Na+ ion. Additional coordination is provided to each MnIII centre by a 1,8-C10H6(NSiiPr3)2 [1,8-bis­(triisopropyl­silyl­amido)­naph­tha­lene] ligand and to the Na+ centres by a tetra­hydro­furan mol­ecule. The presence of an additional Na...H—C agostic inter­action potentially contributes to the distortion around the bridging oxide group.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	International Union of Crystallography
ISSN:	0108-2701
Last Modified:	12 Jul 2024 13:45
URI:	https://orca.cardiff.ac.uk/id/eprint/170286

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