A transition metal-gallium cluster formed: via insertion of "gaI"

Blundell, Toby J., Taylor, Laurence J., Valentine, Andrew J., Lewis, William, Blake, Alexander J., McMaster, Jonathan and Kays, Deborah L. ORCID: https://orcid.org/0000-0002-4616-6001 2020. A transition metal-gallium cluster formed: via insertion of "gaI". Chemical Communications 56 (58) , pp. 8139-8142. 10.1039/D0CC03559A

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Abstract

The reaction between a two-coordinate Co(II) diaryl complex and “GaI” affords 2,6-Pmp2C6H3CoGa3I5, in a new geometry for a heavier group 13-transition metal cluster. Experimental and computational investigations show that this compound is best described as a nido metalla-group 13 cluster.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date of Acceptance:	9 June 2020
Last Modified:	12 Jul 2024 13:45
URI:	https://orca.cardiff.ac.uk/id/eprint/170290

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