Iron(II)-catalyzed hydroamination of isocyanates

South, Amy J., Geer, Ana M., Taylor, Laurence J., Sharpe, Helen R., Lewis, William, Blake, Alexander J. and Kays, Deborah L. ORCID: https://orcid.org/0000-0002-4616-6001 2019. Iron(II)-catalyzed hydroamination of isocyanates. Organometallics 38 (21) , 4115–4120. 10.1021/acs.organomet.9b00393

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Abstract

A two-coordinate Fe(II) m-terphenyl complex acts as a precatalyst for the hydroamination of isocyanates, affording urea and biuret derivatives, with product selectivity accomplished via modification of the reaction conditions. Using a more nucleophilic amine facilitates the insertion of up to four isocyanates into the N–H bond, affording triuret and tetrauret derivatives.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	American Chemical Society
ISSN:	0276-7333
Last Modified:	11 Jul 2024 15:45
URI:	https://orca.cardiff.ac.uk/id/eprint/170338

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