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Modified polymethyl methacrylate as a sustainable medium for capturing carbon dioxide

Ibraheem, Hanan A., El-Hiti, Gamal A., Yousif, Emad, Ahmed, Dina S. and Kariuki, Benson M. ORCID: https://orcid.org/0000-0002-8658-3897 2024. Modified polymethyl methacrylate as a sustainable medium for capturing carbon dioxide. Materials Letters 372 , 137031. 10.1016/j.matlet.2024.137031

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Abstract

This study evaluates the potential of modified polymethyl methacrylate (PMMA) materials, which incorporate organotin moieties pendant on the polymeric chains, as media for carbon dioxide storage. The PMMA containing a triphenyltin moiety has the largest specific surface area (SBET=11.618 m2/g) in comparison to the polymers containing tributyl (5.287 m2/g) and trimethyl (4.881 m2/g) residues. The PMMA with the triphenyltin moiety proved to be the most efficient material in capturing carbon dioxide (34.8 cm3/cm, 6.8 wt%), which is attributed to its relatively high surface area and pore volume and diameter compared to the others.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Schools > Chemistry
Publisher: Elsevier
ISSN: 0167-577X
Date of First Compliant Deposit: 23 September 2024
Date of Acceptance: 17 July 2024
Last Modified: 18 Jul 2025 01:45
URI: https://orca.cardiff.ac.uk/id/eprint/172330

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