Flow electrosynthesis of phosphinamides and phosphoramidates through P–N coupling †

Boruah, Tribani, Ishizeki, Ren, Roldan, Alberto ORCID: https://orcid.org/0000-0003-0353-9004, Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831 and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2024. Flow electrosynthesis of phosphinamides and phosphoramidates through P–N coupling †. Green Chemistry 26 (23) , pp. 11722-11727. 10.1039/d4gc04450a

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Abstract

A robust flow electrochemical methodology operating under mild reaction conditions for P–N and P–O oxidative coupling has been developed. Potentiostatic and galvanostatic electrolyses were used to investigate reactant redox behaviour, showcasing a broad substrate scope (47 examples, up to 85% yield) across various chemical contexts.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Cardiff Catalysis Institute (CCI) Chemistry
Additional Information:	License information from Publisher: LICENSE 1: URL: https://creativecommons.org/licenses/by/3.0/, Start Date: 2024-10-18
Publisher:	Royal Society of Chemistry
ISSN:	1463-9262
Date of First Compliant Deposit:	30 October 2024
Date of Acceptance:	17 October 2024
Last Modified:	10 Dec 2024 13:59
URI:	https://orca.cardiff.ac.uk/id/eprint/173520

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