XPS insight note: Multiplet splitting in X‐Ray photoelectron spectra

Isaacs, M. A., Graf, A. and Morgan, D. J. ORCID: https://orcid.org/0000-0002-6571-5731 2025. XPS insight note: Multiplet splitting in X‐Ray photoelectron spectra. Surface and Interface Analysis 10.1002/sia.7383

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Abstract

ABSTRACTPhotoelectron spectra can be complicated by the presence of final state effects, leading to the misinterpretation of spectra especially by analysts new to the field. In this insight note, we present a précis on the topic of multiplet splitting, a phenomenon that can produce—especially when coupled with the presence of shake‐satellites—complex spectra that may be readily misinterpreted by those new to the field of X‐ray photoelectron spectroscopy.

Item Type:	Article
Date Type:	Published Online
Status:	Published
Schools:	Schools > Chemistry
Additional Information:	License information from Publisher: LICENSE 1: URL: http://creativecommons.org/licenses/by/4.0/, Start Date: 2025-02-10
Publisher:	Wiley
ISSN:	0142-2421
Date of First Compliant Deposit:	21 February 2025
Date of Acceptance:	28 January 2025
Last Modified:	04 Mar 2025 08:26
URI:	https://orca.cardiff.ac.uk/id/eprint/176378

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