Ali, Rojan, Matsui, Kai, Šadauskis, Jānis, Catherall, Amanda and Wirth, Thomas  ORCID: https://orcid.org/0000-0002-8990-0667
2025.
Flow electrochemical oxidation of N -nitrosamines to N -nitramines.
Chemical Communications
10.1039/d5cc03458b
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License URL: https://creativecommons.org/licenses/by/3.0/
License Start date: 5 August 2025
Official URL: https://doi.org/10.1039/d5cc03458b
Abstract
N-Nitro groups are a key functionality found in most energetic compounds. Conventional synthetic routes require the use of harsh reagents, such as fuming nitric acid. As an alternative, a biphasic electrochemical flow synthesis of N-nitramines from the oxidation of N-nitrosamines using molecular oxygen has been developed, proceeding via paired electrolysis.
| Item Type: | Article |
|---|---|
| Date Type: | Published Online |
| Status: | In Press |
| Schools: | Schools > Chemistry |
| Additional Information: | License information from Publisher: LICENSE 1: URL: https://creativecommons.org/licenses/by/3.0/, Start Date: 2025-08-05 |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| Date of First Compliant Deposit: | 14 August 2025 |
| Date of Acceptance: | 4 August 2025 |
| Last Modified: | 14 Aug 2025 10:45 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/180435 |
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