Wang, Ping, Zhang, Jinzhao, Shuai, Ruiyang, Valera-Medina, Agustin  ORCID: https://orcid.org/0000-0003-1580-7133, Qian, Weijia, Ferrante, Antonio, Qi, Haotian and Wang, Yongzhi
      2025.
      
      Effects of combustor geometry on NH3-CH4 swirling turbulent premixed flames: a combined experimental and large eddy simulation analysis of combustion dynamics and NO emissions.
      International Journal of Hydrogen Energy
      180
      
      
      , 151775.
      10.1016/j.ijhydene.2025.151775
    
  
    
       
    
    
  
  
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Abstract
Ammonia is a promising zero-carbon fuel for gas turbines but is often blended with methane to enhance combustion. This study investigates the previously unexplored influence of combustor geometry on ammonia-methane premixed swirling flames. Experiments and large eddy simulations (LES) were conducted at an equivalence ratio of 0.85 for a blend of 70 vol% NH3 and 30 vol% CH4, comparing rectangular and cylindrical combustors. The results show distinct flame stabilization mechanisms: wall confinement in the rectangular combustor creates fragmented recirculation zones, whereas the cylindrical geometry promotes a coherent swirling flow. Consequently, the cylindrical combustor generated 1.8 × higher NO emissions (experimentally 2045 ppm vs 1127 ppm), attributed to increased OH radical concentration and higher post-flame temperatures that inhibit NO reduction. These findings suggest rectangular combustors can better balance flame stability with reduced emissions under the studied conditions, providing valuable guidance for designing advanced low-NOx combustors using ammonia fuel blends.
| Item Type: | Article | 
|---|---|
| Date Type: | Publication | 
| Status: | Published | 
| Schools: | Schools > Engineering | 
| Publisher: | Elsevier | 
| ISSN: | 0360-3199 | 
| Date of First Compliant Deposit: | 1 October 2025 | 
| Date of Acceptance: | 26 September 2025 | 
| Last Modified: | 02 Oct 2025 09:00 | 
| URI: | https://orca.cardiff.ac.uk/id/eprint/181415 | 
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